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PNNL develops metal-free peptoid assemblies for carbon mineralization

PNNL reported on October 14 on crystalline peptoid nanosheets and nanotubes that mimic enzymes without metal cofactors. Histidine-inspired catalytic groups promoted conversion of carbon dioxide into bicarbonate and carbonate-mineral formation in the presence of calcium.

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Carbon-13 nuclear magnetic resonance measurements showed accelerated mineralization, with nanosheets eliminating the induction period before mineral formation. The assemblies displayed thermal and chemical stability. This is materials and catalysis research; the source reports no commercial capture plant, emissions-removal volume or industrial cost.

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    PNNL develops metal-free peptoid assemblies for carbon mineralization

    PNNL reported on October 14 on crystalline peptoid nanosheets and nanotubes that mimic enzymes without metal cofactors. Histidine-inspired catalytic groups promoted conversion of carbon dioxide into bicarbonate and carbonate-mineral formation in the presence of calcium.

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